hyd-RO-dose displays results in 3D format -- Calcite Sat versus pH, % Recovery
hyd-RO-sat
Water Chemistry Modelling
Scale Prediction 
& Treatment Optimization
for Reverse Osmosis Systems


SOPHISTICATED INDICES AND OLD STANDARDS
We all have favorite, or at least familiar indices which assist in the assessment of the scale potential of a water, and which provide some insight into the impact of concentrating it, heating it, or changing pH. The common indices provide an excellent starting point for evaluating a water chemistry and scale potential. Prior to the advent of cost effective personal computers, sophisticated indices were beyond the reach of most water chemists. The indices and calculation methods practical for manual use are simplifications which include assumptions that can cause misleading interpretations, especially in high TDS brines, and limit the applicability of the indices.

hyd-RO-sat brings main frame calculation power for water treatment to the level of the PC, eliminating (or at least greatly minimizing) the need for simplification and sometimes misleading assumptions.



Use hyd-RO-sat to Minimize Scale Potential with Acid Feed


WHY SOPHISTICATED INDICES?
The old standards provide insight into scale potential for single scales. They are limited to simple estimation methods, and do not take into account phenomena such as "Common Ion Effects," which are prevalent in high TDS brines. Sophisticated indices such as ion association model saturation levels account for these effects and can be calculated for most foulants. Ion association model indices also provide a more realistic view of scale potential than the old standards. They base their calculations upon free ion concentrations rather than the total analytical values used for most indices. In natural waters, calcium (for example) is not typically found as 100% free calcium. A portion of the calcium may be bound to sulfate, another portion of the total may be tied up by bicarbonate, hydroxide or other species with which it associates. Ions in water are typically associated with other ions. Indices calculated based upon total ion present (e.g. total analytical calcium) can be misleading. In high TDS waters, they can grossly over estimate the driving force for scale formation and growth. The ion association model indices overcome this shortcoming by estimating the concentration of free ions, and calculating indices using the free concentration rather than the total. Ion association model indices improve the realism, and the accuracy, of scale prediction in this manner.

hyd-RO-sat uses an ion association model to extend the applicable ionic strength for calculations, and to provide consistent, reproducible indices for common, and not so common, scale forming species. 


 
 

Use hyd-RO-sat to Evaluate The Ability of 
Scale Inhibitors To Increase Recovery




 

Scale Inhibitor Models Available for the hyd-RO-dose Series

Calcium carbonate inhibitors
AMP (amino tris methylene phosphonic acid) Dequest 2000
HEDP (hydroxy ethylidene diphosphonic acid) Dequest 2010
PBTC (phosphono butyl tricarboxylic acid) Bayhibit AM
PAA (polyacrylic acid, low molecular weight) Acumer 1000, AR-900A
PMA (poly maleic anhydride) Bellasol S-20
modified PMA  Bellasol S-29
Calcium sulfate inhibitors
PCA (phosphono carboxylic acid) Bellasol 
Generic PAA  
Barium sulfate inhibitors
Generic PAA  
Corrosion rate models
mild steel  untreated

Acknowledgments
Acumer is a trademark of the Rohm & Haas Company
Aquatreat is a trademark of the ALCO Chemical Division of National Starch
Bayhibit is a trademark of Bayer
Belclene, Belcor, Belsol, and Belsperse are trademarks of FMC
Dequest is a trademark of Monsanto Chemical Company
Goodrite is a trademark of the BFGoodrich Company
Versa is a trademark of the National Starch and Chemical Company
hyd-RO-sat and hyd-RO-dose are trademarks of French Creek Software
 



ION ASSOCIATION MODEL SATURATION LEVELS AND MOMENTARY EXCESS VALUES CALCULATED BY 
hyd-RO-sattm and the hyd-RO-dosetm Series

Calcite CaCO3
Aragonite CaCO3
Gypsum CaSO4.2H2O
Anhydrite CaSO4
Witherite BaCO3
Barite BaSO4
Celestite SrSO4
Strontianite SrCO3
Amorphous Silica SiO2
Hydroxylapatite Ca5(PO4)3(OH)
Tricalcium phosphate Ca3(PO4)2
Brucite Mg(OH)2
Fluorite CaF2
Strengite Fe(PO4)2
Siderite FeCO3
Amorphous Ferric hydroxide Fe(OH)3
Iron sulfide FeS

OLD STANDARDS & SIMPLE INDICES
Calculated by hyd-RO-sat and hyd-RO-dose

Langelier Saturation Index 

Stiff Davis Index

Ryznar Stability Index 

Practical (Puckorius) Scale Index

Larson-Skold Corrosivity Index 



hyd-RO-dose and hyd-RO-dose Computer Requirements

CPU 486 DX2-66 or better, Pentium 100 recommended
Math coprocessor Required for all versions due to heavy number crunching
Memory (RAM) 8 megabytes Windows™ 3.1, 16 megabytes Windows 95, 32 megabytes Windows NT
Hard Drive Storage All versions require two (2) to four (4) megabytes of hard drive storage, depending upon version, options, and number of systems evaluated.
Video Super VGA resolution recommended (800x600 or 1024x768), VGA resolution minimum (640x480)

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